Reconciling mechanical robustness with controlled end-of-life degradability represents a central challenge in the design of sustainable polymeric materials. Here, we develop a solvent-free in situ ring-opening polymerization strategy for incorporating size-specific cyclic poly(phenylene sulfide) macrocycles (c[n]PS,...
Bin Sun, Jia-Xiong Liu, Kenji Yamaoka et al.· ACS Sustainable Chemistry &a...· 0 citations
Designing sustainable polymer materials that combine mechanical robustness with recyclability remains a significant challenge. Here, we report a cellulose-based Diels–Alder (DA) cross-linked network that integrates structural strength, thermoreversible recyclability, and tunable biodegradability. Cellulose was functi...
Stimuli-responsive hydrogels capable of reversible volume change are promising materials for soft actuators, sensors, and biomedical systems. However, conventional poly(N-isopropylacrylamide) (PNIPAAm) hydrogels typically exhibit slow thermal responses due to limited water transport and the formation of a dense skin...