Ligand-protected clusters with atomically precise structures serve as prototypical models for understanding versatility at the bottom of the nanoscale regime. Here, we set to investigate the impact of ligand identity on the structural, bonding, and optical properties based on Au13Cl2 and Au13 cluster cores coordinate...
Alvaro Muñoz-Castro· Journal of Physical Chemistr...· 0 citations
Metal halide perovskites have exhibited considerable potential for solar-driven photocatalytic CO2 reduction, yet their practical application is largely hindered by lead toxicity and severe charge recombination. In this work, we report the synthesis and screening of lead-free halide double perovskite Cs2AgBiX6 (CABX, X...
Zhe Wang, Tang Tang, Jian-Pei Feng et al.· Chemistry - An Asian Journal· 0 citations
Three-dimensional (3D) aromaticity provides a powerful framework for understanding the stability and electronic structures of superatomic clusters, yet how such aromaticity evolves during atom-by-atom structural growth remains poorly understood. Herein, we report two endohedral zirconium-antimony Zintl clusters, [Zr@Sb...