Interfacial Polarization and Charge Transfer in Al13 Superatom–Organic Interfaces: Role of Frontier Orbital Overlap
Superatoms (SAs) have emerged as atomically precise building blocks for functional materials; however, their interfacial electronic interactions with organic substrates remain poorly understood, particularly in the absence of ligand protection. While most reported SAs are stabilized by ligands, ligand-free SAs provid...