Enantio- and Regioselective Ni-Catalyzed Hydroarylation of Alkenes and Alkynes to Form C–N Axially Chiral Heterobiaryls
C–N axially chiral heterobiaryls are highly valuable yet synthetically challenging scaffolds. Atroposelective hydroarylation represents an ideal strategy for their construction, offering both high step- and atom-economy. Herein, we report an enantio- and regioselective Ni-catalyzed hydroarylation of unactivated alken...