C. J. Chang

From oxido-bridged dimers to hydrogen-bonded assemblies: steric control of self-assembly in cis-dioxovanadium(v) Schiff-base complexes

cis-Dioxidovanadium(v) (cis-VO2+) moieties are among the most fundamental structural units in vanadium(v) coordination chemistry, yet the factors governing their nuclearity, self-assembly, and crystallization remain poorly understood. Here, we investigate these factors in a family of cis-VO2+ Schiff-base complexes deri...