C. T. Đoàn

Enzymatic metal hydride and hydrogen atom transfer reactions: recent developments for synthetic applications.

Metal-hydrogen (M-H) intermediates are central to many organometallic processes but only play a transient role in metalloenzyme mechanisms in Nature and cannot be used directly for synthetic purposes. However, recent advances have revealed that robust zinc and iron metalloproteins can be repurposed to access M-H interm...