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Carole Duboc

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Open access Sep 2026

Electrochemical CO2 reduction by phosphine-modified [FeFe]-hydrogenase models.

[FeFe]-hydrogenase model complexes of the type [Fe2(µ-RS2)CO6], featuring rigid dithiolate ligands, have recently been identified as efficient and selective electrocatalysts for the reduction of CO2 to formate. While substitution of carbonyl ligands by phosphines has been extensively explored to tune the reactivity of...

Guilherme L. Tripodi, Lucile Chatelain, Bas J. Klement et al. · 0 citations
Open access Sep 2026

A Host–Guest Strategy to Achieve Selective and Robust CO2-to-CO Electrocatalysis in Aqueous Media

Heterogeneous materials incorporating molecular catalysts hold strong promise for efficient electrocatalytic CO2 reduction to value-added products. While activity and selectivity are traditionally tuned through ligand design, increasing attention is being paid to the second-coordination sphere, which modulates reacti...

Irene Suarez-Antuña, Guilherme L. Tripodi, G. Szalóki et al. · 0 citations

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