Phosphorene-Supported Rh Carbonyl Hydride Fragments as Efficient Heterogeneous Single-Site Catalysts for Ethylene Hydroformylation: A First-Principles Investigation
Hydroformylation is a 100% atom-economy industrial process that converts olefins and syngas to aldehydes, typically catalyzed by homogeneous Rh phosphine or phosphite complexes, though catalyst recovery and ligand stability remain persistent challenges. Here, we theoretically investigate HRh(CO)2 fragments supported...