Homo/Heterogeneous Dual Active Centers Enable Selective Electrochemical C─N Coupling of CO2 and Nitrate to Formamide.
Electrochemical C─N coupling from carbon dioxide and nitrogen oxoanions offers a sustainable route to value-added amides, yet achieving high selectivity remains challenging due to competing reaction pathways and insufficient substrate activation. Here we report a homo/heterogeneous dual-active-center catalyst that inte...