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Open access Sep 2026

Taming the carbamoyl radical for selective hydrocarbamidation of alkynes via metallaphotoredox catalysis

The direct addition of an amide group across unsaturated C–C bonds remains a persistent challenge in chemical transformations. Although nickel-catalyzed hydrocarbamoylation and hydroamidation reactions of alkynes have been developed under thermal conditions, these protocols typically require formamide and isocyanate as...

Nandita Ahalyan, Pintu Ghosh, Vikash Kumar et al. · 0 citations
Open access Jul 2026

Photocatalytic, Scalable Anti-Markovnikov Hydrocarboxylation of Unactivated Alkenes via Amine-Mediated CO2 •– Generation from Formate

The use of formate salt as a C1 synthon offers a practical and accessible carboxylating reagent relative to the gaseous alternatives. However, photochemical transient CO2 •– generation from formate and its utilization for carboxylation reactions is mostly restricted to the activated alkenes. Herein, we report a general...

Pintu Ghosh, Bikiran Pal, D. Maiti · 0 citations

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