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D. Neumark

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Open access Sep 2026

Revealing Spectral Characteristics of Shared Protons in Deprotonated Glutamic Acid Using Cryogenic Ion Trap Spectroscopy and Anharmonic Calculations

Shared protons in dicarboxylate motifs are essential biological components. Infrared (IR) spectroscopy is the premier tool to probe the OHO vibrations defining these structures, as vibrational frequencies directly reflect the underlying potential surface. Previously, infrared multiple photon dissociation (IRMPD) studie...

Jun-Hao Yu, Shotaro Yoshikawa, Qian-Rui Huang et al. · 0 citations
Open access Aug 2026

Probing the Quantum Nature of Intramolecular Vibrational Energy Redistribution in HCCH-H2CC Isomerization Using High-Resolution Photoelectron Spectroscopy.

High resolution photoelectron spectra of vinylidene anions (H2CC- and D2CC-) are reported using variations on slow electron velocity-map imaging of cryogenically cooled anions (cryo-SEVI). This work builds on previous studies aimed at exploring the coupling between neutral H2CC and HCCH isomers. One-photon photodetachm...

Martin DeWitt, Dong-Zheng Yang, Jascha A. Lau et al. · 0 citations

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