Sequence-Controlled Copolymerization of 6-/7-Membered Cyclic Carbonates with l -Lactide: Wide-Range Regulation of Copolymer Properties
The synthesis of sequence-controlled poly(lactide-carbonate) copolymers via ring-opening copolymerization (ROCOP) of l-lactide (l-LA) with cyclic carbonates under industrially relevant conditions (in bulk and melt) is highly challenging owing to the lack of highly active and thermally stable catalysts. Herein, we sys...