A Dynamic Surface Metal-Organic Framework Electrocatalyst: Potential-Driven Activation of Atomically Defined Au Sites for the Hydrogen Evolution Reaction.
Surface metal-organic frameworks (SMOFs) are promising platforms for catalysis, yet their structural response to electrochemical bias is often overlooked. We report the potential-driven activation of an N-heterocyclic carbene (NHC)-based SMOF on Au(111) for the hydrogen evolution reaction (HER). Operando electrochemica...