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Oct 2026

3 d Transition Metal Contribution to the Magnetic Behavior of Chiral Y6 M x Si2S14 and Tb6CoSi2S14

A series of quaternary rare-earth sulfide materials Y6MxSi2S14 (M = Ti, V, Cr, Mn, Co, Ni) and Tb6CoSi2S14 were synthesized by solid-state methods to investigate the effects of the 3d transition metal on the respective magnetic properties. The elemental composition was confirmed by single-crystal X-ray diffraction (S...

E. Gamage, Ernesto Soto, V. O. Garlea et al. · 0 citations
Open access Jul 2026

Self-organized vacancy order in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Pr</mml:mi> <mml:mn>9</mml:mn> </mml:m

In this work, we report the discovery of a new crystal structure on the Ge-rich side of the Pr-Ge binary phase diagram. Using a high-temperature flux technique, we grew single crystals of $Pr_9Ge_{16}$, which adopt a previously unreported orthorhombic $Fdd$2 structure type featuring ordered Ge vacancies. We present the...

Jayashani S. T. Wickramasinghe, Melissa G. Anderson, Kelci Graville et al. · 0 citations

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