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Author

Fen Gao

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2 papers indexed here

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Sep 2026

Stereodivergent Construction of Adjacent Tetrasubstituted Stereocenters Enabled by CPA-Catalyzed Enantioselective Desymmetric Friedel-Crafts Reaction of α-Aryl-α-fluoro-1,3-indanediones.

Here we report the asymmetric Friedel-Crafts reaction between compounds α-aryl-α-fluoro-1,3-indanediones and indoles, catalyzed by an efficient chiral phosphoric acid catalyst. Using this methodology, a series of cyclic β-fluoroalcohols bearing two adjacent chiral centers were synthesized in up to 95% yield, with excel...

Xing-Pin Wei, Dan Li, Fen Gao et al. · 0 citations
Aug 2026

Yttrium( III )‐Catalyzed Desymmetrization of 2‐Fluoro‐1,3‐indanediones via Allylation towards Chiral 3‐Hydroxyindanones Bearing Quaternary C–F Stereogenic Centers

3‐Hydroxyindanone represents one of the most valuable and privileged cyclic scaffolds in synthetic and medicinal chemistry, which widely exists in a variety of biologically active natural products and pharmaceutical lead molecules. Benefiting from its reactive hydroxyl and carbonyl functional groups, the 3‐hydroxyind...

Ji-Long Tian, Fen Gao, Fang‐Lin Chen et al. · 0 citations

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