Author

Genping Huang

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Open access Sep 2026

Nickel-Catalyzed de novo Synthesis of C─N Atropisomeric Biaryls via Dual Chelation-Assisted Aza-Michael Addition.

The asymmetric construction of C─N bonds using readily available C─H (arene) and N─H (amine) reagents constitutes a modular and flexible synthetic strategy. Nevertheless, de novo synthesis of axially chiral C─N scaffolds via direct C─H/N─H coupling remains a formidable challenge, and it has been previously restricted t...

Xiao-Han Zhu, Yue Shi, Wei Wang et al. · Angewandte Chemie · 1 citation

Open access Aug 2026

Enantioselective Access to Trifluoromethylated Spirocyclopropyl Heterocycles

ABSTRACT Chiral spirocyclopropyl heterocycles have emerged as privileged three‐dimensional structural motifs in medicinal chemistry. Nevertheless, efficient catalytic enantioselective assembly of such compounds still faces considerable synthetic difficulties. Herein, we describe a rhodium‐mediated asymmetric [2+1] cycl...

Yuanhao Zhu, Youzhi Xu, Weitao Zhang et al. · Advancement of science · 1 citation