Author

Gong-Li Tang

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Oct 2026

A Substrate-Permissive Vanadium Haloperoxidase in Type II Polyketide Biosynthesis Unlocks Non-Native Halogenation across Diverse Substrate Scaffolds

Halogenated compounds are prevalent in natural and synthetic molecules, profoundly affecting molecular stability, physicochemical properties, and biological activity. While enzymatic halogenation offers a sustainable and selective synthetic route, its broad application is limited by the narrow substrate scope of the...

Shi-Qi Fang, D. Ding, Qiu-Yue Nie et al. · Journal of the American Chem... · 0 citations

Open access Sep 2026

Functional identification of two cytochrome P450 enzymes involved in diterpenoid oxidation in Ginkgo biloba

The value of the engineered yeast chassis for accelerating the discovery of plant diterpenoid oxidases is highlighted and provides new enzymatic tools for the future biosynthetic production of structurally diverse oxidized diterpenoids.

Lu Chen, Yue Zhang, Zhen Fan et al. · Frontiers in Plant Science · 0 citations

Sep 2026

Biosynthesis of YM-216391 Unveils a Bifunctional α-Ketoglutarate-Dependent Enzyme Catalyzes Hydroxylation and Epimerization in RiPPs

The RiPP-modifying enzyme YmI is reported, a bifunctional Fe/αKGD that catalyzes Cβ-hydroxylation of Phe19 and Cα-epimerization of Ile20 on the precursor peptide YmA toward the formation of YM-216391, unveiling an unprecedented mechanism and novel bifunctionality, markedly expanding the reaction landscape for αKG-depen...

Kai Zhang, Lian Wu, Min-Jie Yang et al. · Journal of the American Chem... · 0 citations