Reticular Construction of Porphyrin-Pyrazolate Frameworks for Markovnikov-Selective Wacker-Type Oxidation of Styrenes.
Reticular chemistry enables construction of metal-organic frameworks (MOFs) with predictable topologies by matching the connectivity and geometry of nodes and linkers. However, extending such design principles to pyrazolate systems remains challenging due to the fixed connectivity and geometric directionality of their...