Spatially Confined Molybdenum Catalysts in Hollow ZSM-5 Zeolites via Si/Al Ratio-Tailored Desilication-Recrystallization for High-Efficiency Propane Dehydrogenation
The rational design of highly stable and selective molybdenum-based catalysts for propane dehydrogenation (PDH) remains a major challenge, due to severe intraparticle mass transfer limitations and rapid deactivation driven by active site volatilization and coking. Here, we report a controlled desilication-recrystalli...