Author

Gwangsu Bak

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Open access Sep 2026

Cation-Directed Mechanistic Bifurcation in Electrochemical CO2 Reduction: Rate-Determining Step Switching and Opposite Temperature Dependencies on Ni Single-Atom Catalysts

While electrolyte cations are widely recognized as a key regulator of electrochemical CO2 reduction (CO2RR) activity, whether different cation classes merely modulate reaction rates or fundamentally redirect the underlying rate-determining step (RDS), and consequently the system's response to environmental variables,...

Sejin Park, Gwangsu Bak, Jiseon Kim et al. · ACS Catalysis · 0 citations