Dynamic Asymmetry in O/N-Coordinated Zn Single-Atom Catalysts Promotes Sabatier-Favorable Urea and Urea Peroxide Electrosynthesis.
Precise regulation of metal‒intermediate binding is essential for selective electrocatalysis, yet conventional symmetric single-atom coordination often limits directional adsorption control. Here we report an asymmetric O/N-co-coordinated Zn single-atom catalyst, Zn-O3N1-C, using symmetric Zn-O4-C as a structural count...