Conformation-Locking in Thiazole-Rich Mixed-Linkage Covalent Organic Frameworks for Spontaneous Exciton Dissociation and Efficient Photocatalysis.
The formidable exciton effect inherent in organic semiconductors fundamentally restricts free charge carrier generation, thereby impeding photocatalytic redox efficiency. Facilitating spontaneous exciton dissociation and lowering exciton binding energy are essential for maximizing charge utilization. Herein, we report...