Author

Jan Langwald

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Open access Aug 2026

Catching Wyckoff’s Phantom: The Peculiar Crystal Structure of Orthorhombic Cs[ICl 2 ]

The crystal structure of the thus far elusive orthorhombic modification of Cs[ICl 2 ] ( Pnma , Z = 4, a = 1042.2(1) pm, b = 647.35(5) pm, c = 870.38(8) pm and V = 587.21(9) Å 3 ) is reported. In contrast to the structure of the known trigonal modification ( R m ), the [ICl 2 ] − anion show...

Jan Langwald, Antonio Frontera, Mathias S. Wickleder · Zeitschrift für anorganische... · 0 citations

Open access Jul 2026

Deriving General Energy Predictors for Pnictogen Bonding.

A comprehensive quantum chemical study is presented to derive energetic predictors for pnictogen (Pn) bonding interactions. We analyzed the interaction energies of the Lewis acids PnF3 and F2PnX, where Pn represents nitrogen through bismuth and X represents chlorine, bromine, or iodine, acting as σ-hole donors with a d...

Jan Langwald, Antonio Frontera · Chemistry · 0 citations