Nitrene generation and transfer for unnatural biosynthesis in living cells.
It is shown that chemical reactions of metabolic intermediates produced intracellularly in living cells can include intermolecular nitrene transfers.
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It is shown that chemical reactions of metabolic intermediates produced intracellularly in living cells can include intermolecular nitrene transfers.
Coumarins and their derivatives possess diverse bioactivities and broad applications in pharmaceuticals, food additives, and materials science. For example, amino-functionalized coumarin derivatives hold significant promise for the development of novel functional materials and drug discovery. However, the microbial bio...
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