Alkoxy Radical-Mediated Alkene Difunctionalization via Electrophotochemical LMCT Catalysis for the Synthesis of Functionalized Ethers.
Alkoxy radical-mediated hydroetherification offers an atom-economical approach for C-O bond construction. However, the difunctionalization of alkenes driven by alkoxy radicals remains elusive due to the inherent challenges associated with the generation and controlled reactivity of these reactive oxygen-centered radica...