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Jun-Rong Zhang

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Oct 2026

Copper-Mediated Valence Tautomerism Enables α -C(sp3)–H Alkylation of 1,3-Dicarbonyl Compounds and Tryptophans via Photocatalysis

Carbonyl α-C(sp3)–H functionalization is a key approach to access functionalized pharmaceuticals, agrochemicals, and bioactive peptides. Conventional two-electron enol tautomerization strategies for this transformation often suffer from harsh reaction conditions and limited substrate tolerance. While valence tautomer...

Jun-Rong Zhang, Ya Xiao, Xiang Zhou et al. · 0 citations

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