Kevin Klaus Stefanoni

Redox-Tuned Oxycarbamates Enable Divergent C─N and C─C Functionalization of Indolizines Under Photoredox Catalysis With Green Light.

Nitrogen-centered radicals (NCRs) provide direct access to C─N bonds, but their broader use remains limited by the need for strongly reducing photocatalysts, high-energy irradiation, and incomplete control over competing radical transfer pathways. Here we show that nonafluoromesitylsulfonyl (Nms)-substituted oxycarbama...