Bridging molecular and heterogeneous catalysis: metallolinker-assembled and post-synthetically metalated covalent organic frameworks for photocatalytic CO2 reduction
Photocatalytic carbon dioxide reduction (PCO 2 RR) represents a promising approach for solar-to-chemical energy conversion and carbon utilization, yet catalyst development remains limited by the trade-off between the molecular precision of homogeneous complexes and the robustness of heterogeneous materials. Metallo...