Induced-Fit for Oxygen Adsorption: Flexible Conjugated Microporous Polymers With Self-Adaptive Active Sites for H2O2 Photosynthesis.
Photocatalytic hydrogen peroxide (H2O2) synthesis via oxygen reduction reaction (ORR) offers a sustainable alternative to energy-intensive anthraquinone processes. However, its efficiency is hindered by poor selectivity and instability stemming from reactive superoxide intermediates through the two-step two-electron (2...