Knowledge-Guided Autonomous Discovery of Microenvironment-Tuned Metal–Organic Framework Photocatalysts
Designing second-sphere microenvironments that promote proton-coupled electron transfer is central to catalysis yet difficult to achieve in porous solids, such as metal–organic frameworks (MOFs). Here, we report an end-to-end workflow that couples literature-guided large-language-model (LLM) reasoning with real-time...