Site‐Specific Molecular Engineering Redirects Radical Pathways for Selective Photocatalytic Coupling of Methane to C2+ Hydrocarbons
ABSTRACT Toward carbon neutrality, multi‐carbon synthesis from photo‐driven oxidative coupling of CH4 (POCM) remains a formidable challenge due to the activity‐selectivity trade‐off, originating from sluggish surface reaction kinetics and uncontrolled reactive radical reactions. Herein, alkyl thiols (C9SH) were site‑sp...