Mechanistic Insight into the Acidic/Redox Modulation of Vanadium-Substituted Dawson Polyoxometalates Enabling Overall Conversion of Larch Lignocellulose
Developing structurally well-defined homogeneous catalysts for one-pot lignocellulose depolymerization remains a significant challenge. Herein, V─Mo polyoxometalate (POM) molecules with a Dawson structure have been designed through “metal-to-metal” replacement of addendum MoVI by different amounts of VV to adjust the...