Enzyme-Directed Architecture–Property Design of Starch-Based Bioplastics: Mechanisms, Performance Trade-Offs, and Scalability Constraints
Starch-based bioplastics are renewable and biodegradable, but their wider use is constrained by moisture sorption, humidity-dependent aging, insufficient tensile performance, and weak water- and oxygen barrier stability. This review critically synthesizes the peer-reviewed literature from 2020 to 2026 on enzymatically...