Author

M. Scardamaglia

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Open access Sep 2026

Ligation of Carbon Monoxide at Iron and Cobalt Single-Metal-Atom Sites: Competition for the +1 Oxidation State in a Surface-Confined Organic Network

Cobalt coordination to a FeTPyP monolayer on graphene yields a two-dimensional FeTPyP–Co metal-organic network, stabilizing highly reactive Fe(I) sites within a biomimetic coordination architecture. The assembly process triggers an electronic reorganization that activates the pristine Fe(II) centers, enabling competiti...

A. Namar, B. Roondhe, S. Baronio et al. · The journal of physical chem... · 0 citations

Open access Sep 2026

An Ultrathin Hydroxide Film Governs the Stability and Reactivity of Gold for the Oxygen Evolution Reaction.

Surface oxidation of noble metals under electrochemical conditions has a decisive impact on the performance of electrocatalysts for electrolyzers and fuel cells. However, the experimental detection of such oxides on well-defined model electrodes under operando conditions is a major challenge, limiting our ability to es...

A. Grespi, A. Larsson, A. Ti et al. · ChemPhysChem · 1 citation

Open access Sep 2026

Stabilization of Strongly Reduced Fe(I) Single Atom Species Coordinated in a 2D Self‐Assembled Metal–Organic Network

Stabilization of low‐valent iron centers in atomically defined coordination environments remains a major challenge in the design of reactive metal–organic materials. Here, we report the rational stabilization of Fe(I)‐N 4 single sites in a graphene‐supported, two‐dimensional metal–organic network assembled from F...

A. Namar, B. Roondhe, M. De Col et al. · Advanced Functional Material... · 0 citations