Ligand-Dependent Electronic Modulation of Conjugated Metal-Organic Frameworks Enables Efficient Electrocatalytic Nitric Oxide Reduction to Ammonia.
Electrochemical reduction of ammonia represents a highly promising approach for transforming harmful environmental pollutants into more valuable products. In this study, we successfully achieved precise control over the environment surrounding single-atom Ni sites by modifying functional groups on ligands. To validate...