[FeFe]-hydrogenase model complexes of the type [Fe2(µ-RS2)CO6], featuring rigid dithiolate ligands, have recently been identified as efficient and selective electrocatalysts for the reduction of CO2 to formate. While substitution of carbonyl ligands by phosphines has been extensively explored to tune the reactivity of...
Guilherme L. Tripodi, Lucile Chatelain, Bas J. Klement et al.· Dalton Transactions· 0 citations
Heterogeneous materials incorporating molecular catalysts hold strong promise for efficient electrocatalytic CO2 reduction to value-added products. While activity and selectivity are traditionally tuned through ligand design, increasing attention is being paid to the second-coordination sphere, which modulates reacti...
Irene Suarez-Antuña, Guilherme L. Tripodi, G. Szalóki et al.· Journal of the American Chem...· 0 citations
Heptazine derivatives are well known for their attractive properties in applications such as organic light-emitting diodes (OLEDs) and flame-retardant materials. However, studies in this field have largely focused on fully symmetrically substituted heptazines. Thus, the coordination chemistry studies for those derivati...
Benjamin Louis, Rana Deeba, Johan Loison et al.· Dalton Transactions· 0 citations
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