Author

Nusrat Jahan Upoma

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2026

Comparative kinetics and DFT study of Zn( <scp>ii</scp> ) metalation in [H 2 TTMAPP] 4+ and [H 2 TMPyP]

[Zn(H 2 O) 5 (OH)] + initiates faster Zn( ii ) metalation of [H 2 TMPyP] 4+ than [H 2 TTMAPP] 4+ via hydrogen bonding, while DFT reveals steric origins of reactivity differences, and DNA binding shifts from intercalation to outside stacking upon metalation.

Md. Samsul Hoque Dany, Nusrat Jahan Upoma, F. Ferdousi et al. · New Journal of Chemistry · 0 citations

Nusrat Jahan Upoma

Comparative kinetics and DFT study of Zn( <scp>ii</scp> ) metalation in [H <sub>2</sub> TTMAPP] <sup>4+</sup> and [H <sub>2</sub> TMPyP]