Despite considerable advances in the well-established benzoin reaction, cross-benzoin reactions remain challenging often due to limited substrate scope, generation of undesired products, and engineered catalysts. Here we outline an entirely new entry path into this useful reaction by demonstrating that readily generate...
Nikolaos Vagkidis, Stephen M. Goodlett, P. R. Schreiner· Journal of the American Chem...· 0 citations
Quantum mechanical tunneling (QMT) can profoundly alter reaction kinetics and ultimately determine the chemical outcome. Therefore, understanding QMT reactivity and extending its relevance to typical laboratory conditions are important goals. In this study, computational screening identified a 3-trifluoromethyl substit...
Sofia Braz, Cláudio M. Nunes, Simon Schlosser et al.· Chemistry· 0 citations
Ion transport in nanostructured materials is critical to numerous applications. In most solid-state ion conductors, polymers, and conventional ionic liquids, ion mobility is closely linked to the strength of ion coordination site interaction energies, which are dictated by ion size and valence. Here, we investigate how...
Sila Alemdar, Jack McAlpine, Hrishikesh Tupkar et al.· ACS Nano· 0 citations
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