Halogen Doping Selectively Induces a High-Spin State in Octahedral Cobalt Sites for Boosting Electrochemiluminescence
In luminol-dissolved oxygen electrochemiluminescence (ECL) systems, endogenous O2 serves as a co-reactant, generating reactive oxygen species (ROS) in situ through cathodic oxygen reduction reaction (ORR). However, this process is constrained by spin-restricted kinetics arising from the spin-forbidden transition from...