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Open access Sep 2026

Dynamic Asymmetry in O/N-Coordinated Zn Single-Atom Catalysts Promotes Sabatier-Favorable Urea and Urea Peroxide Electrosynthesis.

Precise regulation of metal‒intermediate binding is essential for selective electrocatalysis, yet conventional symmetric single-atom coordination often limits directional adsorption control. Here we report an asymmetric O/N-co-coordinated Zn single-atom catalyst, Zn-O3N1-C, using symmetric Zn-O4-C as a structural count...

Sheng-Bo Zhang, Ke Li, Hui Xu et al. · 0 citations
Aug 2026

Janus Cu-Based Alloys with Cooperative Asymmetry for Enhanced C–N Coupling in Electrochemical Urea Synthesis

Electrochemical urea synthesis through C–N coupling is a promising alternative to conventional thermochemical production, yet the activity-determining factors of alloy catalysts under realistic electrochemical conditions remain unclear. Here, we combine density functional theory, solvation-inclusive modeling, and con...

Jinjie Liu, Zixian Li, Yuxuan Yao et al. · 0 citations

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