Heterogeneous energy-transfer metallaphotocatalysis unlocks direct and site-selective thioglycosylation of unprotected thiosugars
The creation of glycoconjugates, particularly well-defined glycopeptides, is crucial for advancing biological research and therapeutic development. However, the direct and selective coupling of unprotected thioglycosides to native biomolecules remains a formidable challenge due to the incompatibility of conventional sy...