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Sri Vidya Vyjayanthi Tallavajhula

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Open access Jul 2026

Chemical Rescue Serves as a Predictive Proxy for Glycosynthase Activity on Glycosidic Bonds via a Shared Glycosyl Oxocarbenium Transition State

It is demonstrated that chemical rescue—the azide-mediated restoration of hydrolytic activity in nucleophile-deficient mutants—serves as a predictive, high-throughput proxy for glycosynthase activity as well as a structural and thermodynamic rationale for using CR to select for transition-state-stabilizing mutations.

Mohit Kumar, C. Bandi, Sri Vidya Vyjayanthi Tallavajhula et al. · 0 citations

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