Electronic Confinement Induced Single Atom Functionality in Hydroxylamine Synthesis Unveiled by Constant Potential Simulation.
Electrochemical nitric oxide (NO) reduction offers a sustainable route for hydroxylamine (NH2OH) synthesis. Single-atom catalysts (SACs), featuring isolated metal centers and weaker adsorbate binding than extended metals, are widely regarded as ideal NH2OH-selective catalysts. However, the recent observation of NH2OH p...