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Open access Oct 2026

Precise molecular sieving in polycrystalline covalent organic framework membranes

Covalent organic frameworks (COFs) unlock opportunities to unite rapid mass transport with molecular-level sieving through membranes. However, achieving long-range crystallographic order within these membranes remains a central challenge that limits their separation precision. Here, we report a monomer-driven strategy...

Xian-Song Shi, Hai-Pei Shao, Xin Zhang et al. · 0 citations
Sep 2026

Tracing Covalent Organic Framework Assembly through Kinetic Deceleration

The formation mechanisms of covalent organic frameworks (COFs) have long been hypothesized but rarely substantiated by direct experimental evidence. Gaining mechanistic insights into this process is essential for the rational design and scalable synthesis of COFs. In this study, we employed the Schiff-base condensati...

Hao-Yuan Zhang, Chun-Qing Ji, Hao Yang et al. · 0 citations

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