Author

Xi-He Bi

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Sep 2026

Stereoselective polysubstituted bicyclo[1.1.0]butane synthesis by rhodium-catalyzed kinetic resolution.

Bicyclo[1.1.0]butanes (BCBs) are a distinctive class of strained small-ring carbocycles of growing importance in synthetic and medicinal chemistry. However, the enantioselective synthesis of polysubstituted BCBs remains a largely unsolved challenge. Herein, we report a general chemical platform for the stereoselective...

Xiao-Long Zhang, Rong-Kai Wu, Zhaohong Liu et al. · Science · 0 citations

Open access Aug 2026

Enantioselective Access to Trifluoromethylated Spirocyclopropyl Heterocycles

ABSTRACT Chiral spirocyclopropyl heterocycles have emerged as privileged three‐dimensional structural motifs in medicinal chemistry. Nevertheless, efficient catalytic enantioselective assembly of such compounds still faces considerable synthetic difficulties. Herein, we describe a rhodium‐mediated asymmetric [2+1] cycl...

Yuanhao Zhu, Youzhi Xu, Weitao Zhang et al. · Advancement of science · 1 citation