Author

Xiao-Jing Zhao

3 papers indexed here

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Sep 2026

Stereodivergent Construction of Adjacent Tetrasubstituted Stereocenters Enabled by CPA-Catalyzed Enantioselective Desymmetric Friedel-Crafts Reaction of α-Aryl-α-fluoro-1,3-indanediones.

Here we report the asymmetric Friedel-Crafts reaction between compounds α-aryl-α-fluoro-1,3-indanediones and indoles, catalyzed by an efficient chiral phosphoric acid catalyst. Using this methodology, a series of cyclic β-fluoroalcohols bearing two adjacent chiral centers were synthesized in up to 95% yield, with excel...

Xing-Pin Wei, Dan Li, Fen Gao et al. · Journal of Organic Chemistry · 0 citations

Aug 2026

Yttrium( III )‐Catalyzed Desymmetrization of 2‐Fluoro‐1,3‐indanediones via Allylation towards Chiral 3‐Hydroxyindanones Bearing Quaternary C–F Stereogenic Centers

3‐Hydroxyindanone represents one of the most valuable and privileged cyclic scaffolds in synthetic and medicinal chemistry, which widely exists in a variety of biologically active natural products and pharmaceutical lead molecules. Benefiting from its reactive hydroxyl and carbonyl functional groups, the 3‐hydroxyind...

Ji-Long Tian, Fen Gao, Fang‐Lin Chen et al. · Chinese journal of chemistry · 0 citations

Sep 2026

Enantioselective Synthesis of gem -Difluorinated Spirobenzazepinoindoles by Chiral Phosphoric Acid (CPA)-Catalyzed Asymmetric Pictet–Spengler Cyclization

7-membered spirobenzazepinoindole frameworks constitute an important family of heterocyclic skeletons with broad utility in pharmaceutical research. Despite their value, the stereoselective synthetic routes toward chiral gem-difluorinated spirobenzazepinoindoles remain unexplored, and a general, efficient constructio...

Hui-Qiao Song, Yan-Ping Gao, Yi Hu et al. · Organic Letters · 0 citations