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Author

Xiao-Qian He

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Open access Aug 2026

Total Synthesis of ent-Kaurenoic Acid Diterpenoids Enabled by Distal Conformational Control in Photoredox Radical Polyene Cyclization.

We report a divergent synthesis of ent-kaurenoic acid-derived diterpenoids enabled by a stereoselective photoredox radical polyene cyclization directed by distal conformational control. A chiral bicyclo[3.2.1]octane unit biases the reactive polyene conformation and controls stereochemical outcome remotely during cascad...

Jinbo Duan, Xiao-Qian He, Xingyue Qi et al. · 0 citations
Sep 2026

Microenvironment Modulation of Single Iron Site in Oxygen Reduction Reaction Revealed by Molecular Model Catalysts.

Precise regulation of the coordination environment in iron-based single-site catalysts (Fe SSCs) is essential for promoting the two-electron oxygen reduction reaction (2e- ORR) toward efficient hydrogen peroxide production. However, the atomic-scale relationship between coordination structure and reaction pathway remai...

Zhi-Qiang Zhang, Tian-Tian Huang, Jun-Qi Song et al. · 0 citations

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