Potential-Driven Dual Effects of Cations Regulate CO2 Reduction: The Interplay between Kinetic Promotion and Steric Effects
Electrode–electrolyte interfacial microenvironments (EEIMs) critically govern the performance of electrochemical CO2 reduction (ECR). However, the potential-driven dynamic distribution of interfacial cations and their reshaping effects on the interfacial water structure and proton-coupled electron transfer kinetics r...