Upright Orientation of Asymmetric Conjugated SAM Enables High-Performance Perovskite Solar Cells.
Self-assembled monolayers (SAMs) are promising hole-transporting interlayers for inverted perovskite solar cells (PSCs) owing to their ultrathin thickness and tunable work function. However, conventional SAMs such as Me-4PACz tend to adopt lying-down or tilted conformations on substrates, leading to disordered dipole o...