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Xiu-Ming Xu

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Oct 2026

Vibrational-Gated Intersystem Crossing in Phenolphthalein Dianion: A TDDFT Insight into the Fluorescence Quenching Mechanism

The structural rigidity of molecular frameworks plays a pivotal role in modulating intersystem crossings (ISCs). Here, we systematically investigate the distinct fluorescence behaviors of the phenolphthalein dianion (PHP2–) and the fluorescein dianion (FLU2–)─two structurally analogous xanthene derivatives. By employ...

Lu Li, Xiu-Ming Xu, Yu-Xin Guan et al. · 0 citations

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